Delville Marie-Hélène

Personnel CNRS
– Directrice de recherche / Groupe 5
– Researcher ID / Google Scholar / ORCID / ResearchGate / Scopus profile
– contact : prénom-prénom.nom@icmcb.cnrs.fr / poste 8460 (ligne directe 054000+poste)

Skills and know-how : Nanoparticle chemistry / Morphology control / Nano heterodimers / Biomedical applications / Bioimaging / Nanotoxicology / Self-assembly

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Education and scientific position

2015-…. : CNRS Senior scientist (DR1) : Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS 9048, 87 Avenue du Dr A. Schweitzer, 33608 Pessac Cedex FRANCE.
2003-2015 : CNRS Senior scientist (DR2) : Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS 9048, 87 Avenue du Dr A. Schweitzer, 33608 Pessac Cedex FRANCE
1997-2003 : CNRS junior scientist (CR1) : Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS 9048, 87 Avenue du Dr A. Schweitzer, 33608 Pessac Cedex FRANCE
1985-1990 : CNRS junior scientist (CR2) : Laboratoire de Chimie Organique et Organométallique, URA CNRS n° 35, Université Bordeaux 1, 351, cours de la Libération, 33405 TALENCE Cedex
1996-1997 : Postdoctoral fellow : Department of Chemistry and Biochemistry, University of Texas at Austin, Austin TX 78712 USA

1990 : Habilitation à Diriger des Recherches (Université Bordeaux1) : « Radicaux Organométalliques et Electrocatalyse. »
1988 : PhD in Chemistry (Université Bordeaux I) : « Réactions Organométalliques Catalysées par Transfert d’Electron et Applications à la Polymérisation des Alcynes Terminaux. »
1984 : Thèse de 3^ème Cycle (Université de Rennes I) : « Complexes Réservoirs d’Electron Mono- et Bi-nucléaires du Fer(I) : Transferts d’Electron et Valences Moyennes. »

Research activities

My research interests are focused on the fundamental and practical aspects of the synthesis of organic-inorganic colloidal nano-objects with special emphasis on synthesis, shape control, surface functionalization of inorganic nanoparticles & sol-gel chemistry as illustrated below. My research also includes, at the interface between chemistry & biology, their use in biomedical applications, focusing on the synthesis of multimodal nanoparticles for imaging and therapy purposes with some insight in toxicity approaches.

Methods : hybrid materials and nanoparticle synthesis (sol-gel, (microwave assisted) hydrothermal), characterization techniques (zetametry, UV-vis, NMR, XPS, TEM, HRTEM)

Knowledge : coordination chemistry, size and morphology control, sol-gel chemistry, biomedical applications, contrast agent for imaging, toxicity, nanoscience.

National Collaborations
J.P. Delville (Bordeaux, LOMA)
R Oda (Bordeaux, CBMN)
L. Billon (IPREM Pau)
H. Seznec (CENBG, IN2P3)
C. Bergaud (LAAS, Toulouse)
H. Cramail (LCPO Bordeaux))
E. Cloutet (LCPO Bordeaux)
O. Orsen (IPCMS Strasbourg)

International Collaborations
J. Rocha & L. Carlos (Aveiro, Portugal) -> Luminescent NPs (2006-…)
C. Geraldes (Coimbra, Portugal) -> NPS and MRI imaging(2006-…)
M. Takafuji (Kumamoto University) ->Helicoidal nanosystems (2013-…)
MF Ottaviani (Urbino University) -> Hybrid materials (2014-…)
R. Kotsilkova (Bulgarian Acad. of Sciences) -> Hybrid materials (2014-…)
J.  Cheng (School of Mater.Sc. and Eng. Wuhan, China) -> QDs et leurs applications (2016-…)
L. Chen (Dpt of Elect. & Elect. Eng., SUSTech. Shenzhen) -> QDs et leurs applications (2017-…)
K. Wang (Dpt of Elect. & Elect. Eng., SUSTech. Shenzhen) -> QDs  et leurs applications (2017-…)
X.W. Sun (Dpt of Elect. & Elect. Eng., SUSTech. Shenzhen) -> QDs  et leurs applications (2017-…)

Scientific production and supervision

145 peered articles/ 2 review articles/ 22 proceedings/ 4 patents/ 8 book chapters/2 vulgarization articles

70 invited talks in national or international conferences / 67 seminars in France or abroad

Number of theses : 17 in all, 1 on going

10 Relevant publications

1. Smart Control of Monodisperse Stöber Silica Particles: Effect of Reactant Addition Rate on Growth Process. Nozawa, K., Gailhanou, H.; Raison, L.; Panizza, P.; Ushiki, H.; Sellier, E.; Delville, J. P.; Delville, M. H.* Langmuir, 2005, 21 (4) 1516-1523. https://pubs.acs.org/doi/abs/10.1021/la048569r
2. Fine Tuning of the Relaxometry of γ-Fe₂O₃ Nanoparticles: Nanoparticles by Tweaking the Silica Coating Thickness. Pinho, S. L. C.; Pereira, G. A.; Voisin, P.; Kassem, J.; Bouchaud, V.; Etienne, L.; Peters, J. A.; Carlos, L. D.; Mornet, S.; Geraldes, C. F. G. C.;* Rocha, J.;* Delville, M.-H.,* ACS Nano 2010, 4, (9) 5339-5349. 1021/nn101129r
3. Synthesis and characterization of rare earth orthoferrite ReFeO₃ nanoparticles for bioimaging.Sonia L.C. Pinho, João S. Amaral, Alain Wattiaux, Mathieu Duttine, Luís D. Carlos, João Rocha, Marie-Hélène Delville, Carlos F.G.C. Geraldes.Eur. J. Inorg. Chem. 2018, 3570–3578.   (2.507)
4. Electrochromic devices based on in situ polymerized EDOT and Prussian Blue: influence of transparent conducting oxide and electrolyte composition-towards up-scaling. Duluard, S.; Celik-Cochet, A.; Saadeddin, I.; Labouret, A.; Campet, G.; Schottner, G.; Posset, U.; Delville, M.-H.,* New Journal of Chemistry 2011, 35, 2314-2321. 1039/c1nj20231f
5. Short Gold Nanorods Growth Revisited: The Critical Role of Bromide Counter Ion.Si S.; Leduc C.; Delville M.-H.; and Lounis B.Chem. Phys. Chem., 2012, 13, 193 – 202.
6. In situ quantification of diverse titanium dioxide nanoparticles unveils selective endoplasmic reticulum stress-dependent toxicity Simon, M.; Saez, G.; Muggiolu, G.; Lavenas, M.; Le Trequesser, Q.; Michelet, C.; Devès, G.; Barberet, P.; Chevet, E.; Dupuy, D.; Delville, M.-H.;* Seznec, H.,*. Nanotoxicology 2017, 11, 134-145. (7.913) 10.1080/17435390.2017.1278803
7. Gold Nanoparticles Forming 3D Helical Superstructures with Controlled Morphology and Strong Chiroptical Property.Cheng, J.; Le Saux, G.; Gao, J.; Buffeteau, T.; Battie, Y.; Barois, P.; Ponsinet, V.; Delville, M.-H.; Ersen, O.; Pouget, E.; Oda, R., GoldHelix : ACS Nano 2017, 11, 3806-3818.  10.1021/acsnano.6b08723
8. Design of Metal@Titanium Oxide Nano-Heterodimers by Laser-Driven Photodeposition: Growth Mechanism and Modeling.Bai, Q.; Shupyk, I.; Vauriot, L.; Majimel, J.; Labrugere, C.; Delville, M.-H.;* Delville, J.-P.*,  ACS Nano 2021, 15, 2947−2961. 10.1021/acsnano.0c09155
9. Ligand-induced Chirality in Asymmetric CdSe/CdS Nanostructures: A Close Look at Chiral Tadpole, Junjie Hao, Yiwen Li, Rulin Liu, Jiagen Li, Haocheng Liu, Qiushi Wang, Huan Liu, Marie-Hélène Delville, Tingchao He, Kai Wang, Xi Zhu, Jiaji Cheng. ACS Nano 2020, 14, 8, 10346–10358 https://doi.org/10.1021/acsnano.0c03909
10. Optically Active CdSe/CdS NPLs Exhibiting Both Circular Dichroism and Circularly Polarized Luminescence. Junjie Hao, Fenghuan Zhao, Qiushi Wang, Jiaying Lin, Peixian Chen, Junzi Li,Dongxiang Zhang, Meijuan Chen, Peizhao Liu, Marie-Helene Delville,* Tingchao He,* Jiaji Cheng* and Yiwen Li*. Adv. Optical Mater. 2021, 2101142 . 10.1002/adom.202101142

Scopus profile

 

Edition

 Co-Editor of the Summer school book o, « Fluides Supercritiques et les Matériaux » (Biarritz) (ISBN 2-905-267-31-3) (200 samples) 1999.

 Guest Editor for a special issue Nanotechnol. Rev : http://www.degruyter.com/view/j/ntrev.2015.4.issue-6/issue-files/ntrev.2015.4.issue-6.xml

 Co–Editor of a book in two volumes untitled: Delville, M.-H.; AndreasTaubert, Hybrid Organic-Inorganic Interfaces: Toward Advanced Functional Materials, Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim Germany, 2018; p 1096. https://www.wiley.com/en-us/Hybrid+Organic+Inorganic+Interfaces%3A+Towards+Advanced+Functional+Materials%2C+2+Volumes-p-9783527342556

Coordination background over the past fifteen years

 Organisation/animation of national and international meetings:

• 2003:    Organiser of CNRS Summer School: Hybrid Materials: from properties to applications.
• 2006:    Co-organiser of the 11th International Conference on Electroanalysis ;
• 2007:    Co-organiser :  1^st Summer school: NanoObjects at Interfaces, (NOIS)
• 2011:    Co-organiser :  2^nd Summer school: NanoObjects at Interfaces, (NOIS)
• 2013 :   Organiser: Training School « Characterisation Techniques for Interfaces in Hybrid Materials» : (Bordeaux, 2-5 avril ).
• 2013 :   Organiser: workshop «The interface in hybrid & biohybrid materials:role & characterization» (Madrid, SPAIN, 2‐3 Sept.)
• 2014 :   Organiser:  workshop « Modelling and characterization of interface » (Urbino, ITALY 3 -5 March  2014)
• 2014 :   Organiser: workshop « Role of interface in synthesis and applications » (Turku, FINLAND 16-18 June 2014)
• 2014 :   Organiser: workshop « Applications of Hybrid Materials Interfaces » (Istanbul, TURKEY 15-17 September 2014)
• 2014 :   Organiser: workshop « Modelling and characterization of interface » (Urbino, ITALY 3 -5 March  2014)
• 2015 :   Organiser: workshop « Nanostructured Hybrid Materials II: reinforced 3D structures, smart composites, self-healing (Heraklion, GREECE 22-24 April)
• 2015 :   Organiser: Training School « Bottom-up approaches of hybrid materials interfaces: preparation & design »: (Ljubljana, 26-28 May).
• 2015 :   Organiser:  workshop « Biomedical, health and bio-related applications of hybrid materials » (Barcelona, SPAIN 8-9th June)
• 2016 :   Organiser: Training School Functional hybrid materials: structure elucidation from molecular to macro level»: (Stockholm, 25-27 May 2016).
• 2016 :   Organiser: workshop « Nanostructured materials: coatings, surfaces, bioceramics/-composites, membranes »  Vilnius, Lithuania 14-16 March 2016),
• 2016 :   Organiser: workshop « Interface in Hybrids for Sustainable Energy &  Applications »(Prague, Czech Republic18 – 19 July 2016)
• 2018 :   Organiser: symposium au MRS Spring meeting de Phoenix USA, Titre : Functional (bio)polymers in energy and environment applications ( 2-6 avril)

 Project  coordination at National and European levels:

• 2004-2007:  Network of Excellence: FAME: Task leader in a WP
• 2004-2007: Work Package leader in FP6 STREP : Nanoeffects  (630 k€)
• 2008-2012: Participant in FP7 IP : INNOSHADE
  
• 2012-2016: Chair of a European COST Action MP1202 untitled “Rational design of hybrid organic-inorganic interfaces: the next step towards advanced functional materials”: http://www.cost-hint.cnrs.fr/
• 2014- : Chair of the International Associated Laboratory: LAFICS
• 2010-2013: Project leader of a National research project  (ANR) (3 years)
• 2011-2014: Work Package leader in ANR projects
• 2016-2020: Project leader of a National research project  (ANR) (4 years).